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Solution hardening of lead single crystals at liquid air temperature

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Solution hardening of lead single crystals at liquid air temperature

Auteurs : RBID : ISTEX:10853_1969_Article_BF00550210.pdf

Abstract

Single crystals of lead with either thallium, indium, bismuth, cadmium, mercury or antimony were tested in tension in liquid air. The critical resolved shear stress τ0 increases linearly with increasing solute content c in a limited concentration range. The increase Δτ0/ΔC is lowest for lead-thallium and highest for lead-antimony. When log Δτ0/ΔC is plotted against log (sf + elf) where sf*[(d1)Pb − (d1)sol/(d1)Pb]10Pb, d1 being the closest distance of approach, and elf = ΣEn, ΣEn being the sum of the electronegativities of solvent and solute, a straight line of slope 2 results. A similar result is obtained with data from the literature for single crystals of copper alloys and of magnesium alloys. However in these cases a different size factor has to be used.

DOI: 10.1007/BF00550210

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<div type="abstract" xml:lang="eng">Single crystals of lead with either thallium, indium, bismuth, cadmium, mercury or antimony were tested in tension in liquid air. The critical resolved shear stress τ0 increases linearly with increasing solute content c in a limited concentration range. The increase Δτ0/ΔC is lowest for lead-thallium and highest for lead-antimony. When log Δτ0/ΔC is plotted against log (sf + elf) where sf*[(d1)Pb − (d1)sol/(d1)Pb]10Pb, d1 being the closest distance of approach, and elf = ΣEn, ΣEn being the sum of the electronegativities of solvent and solute, a straight line of slope 2 results. A similar result is obtained with data from the literature for single crystals of copper alloys and of magnesium alloys. However in these cases a different size factor has to be used.</div>
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<abstract lang="eng">Single crystals of lead with either thallium, indium, bismuth, cadmium, mercury or antimony were tested in tension in liquid air. The critical resolved shear stress τ0 increases linearly with increasing solute content c in a limited concentration range. The increase Δτ0/ΔC is lowest for lead-thallium and highest for lead-antimony. When log Δτ0/ΔC is plotted against log (sf + elf) where sf*[(d1)Pb − (d1)sol/(d1)Pb]10Pb, d1 being the closest distance of approach, and elf = ΣEn, ΣEn being the sum of the electronegativities of solvent and solute, a straight line of slope 2 results. A similar result is obtained with data from the literature for single crystals of copper alloys and of magnesium alloys. However in these cases a different size factor has to be used.</abstract>
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